ChemInform Abstract: A Pinene‐Based Chiral Auxiliary for α‐Alkylation and Aldol Reactions: An Unexpected Effect of the Base on the Stereoselectivity.
Identifieur interne : 001936 ( Main/Exploration ); précédent : 001935; suivant : 001937ChemInform Abstract: A Pinene‐Based Chiral Auxiliary for α‐Alkylation and Aldol Reactions: An Unexpected Effect of the Base on the Stereoselectivity.
Auteurs : Sergio Pinheiro [Brésil] ; Clara B. S. S. Goncalves [Brésil] ; Marcelo B. De Lima [Brésil] ; Florence M. C. De Farias [Brésil]Source :
- ChemInform [ 0931-7597 ] ; 2001-02-20.
English descriptors
- KwdEn :
- Aldol, Aldol reaction, Alkyl, Alkyl bromides, Alkylation, Alkylation reaction, Benzaldehyde, Bromide, Chiral, Deprotonation, Diastereoselective, Diastereoselective syntheses, Diastereoselectivities, Enantioselective, Enantioselective syntheses, Enantioselective syntheses diastereoselective syntheses, Ester, Facial stereoselectivities, Farias, Fluminense, Goncalves, Incl, Inst, Janeiro, Kinetic deprotonation step, Lima, Ltmp, Marcelo, Moderate diastereoselectivities, Niteroi, Pinenebased, Pinenebased ester, Pinheiro, Quim, Sergio, Stereochemistry, Stereoselectivities, Stereoselectivity, Tetrahedron, Tions, Unexpected decrease, Univ.
- Teeft :
- Aldol, Aldol reaction, Alkyl, Alkyl bromides, Alkylation, Alkylation reaction, Benzaldehyde, Bromide, Chiral, Deprotonation, Diastereoselective, Diastereoselective syntheses, Diastereoselectivities, Enantioselective, Enantioselective syntheses, Enantioselective syntheses diastereoselective syntheses, Ester, Facial stereoselectivities, Farias, Fluminense, Goncalves, Incl, Inst, Janeiro, Kinetic deprotonation step, Lima, Ltmp, Marcelo, Moderate diastereoselectivities, Niteroi, Pinenebased, Pinenebased ester, Pinheiro, Quim, Sergio, Stereochemistry, Stereoselectivities, Stereoselectivity, Tetrahedron, Tions, Unexpected decrease, Univ.
Abstract
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Url:
DOI: 10.1002/chin.200108033
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 000329
- to stream Istex, to step Curation: 000329
- to stream Istex, to step Checkpoint: 000599
- to stream Main, to step Merge: 001C11
- to stream Main, to step Curation: 001936
Le document en format XML
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aldol</term>
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<term>Alkyl bromides</term>
<term>Alkylation</term>
<term>Alkylation reaction</term>
<term>Benzaldehyde</term>
<term>Bromide</term>
<term>Chiral</term>
<term>Deprotonation</term>
<term>Diastereoselective</term>
<term>Diastereoselective syntheses</term>
<term>Diastereoselectivities</term>
<term>Enantioselective</term>
<term>Enantioselective syntheses</term>
<term>Enantioselective syntheses diastereoselective syntheses</term>
<term>Ester</term>
<term>Facial stereoselectivities</term>
<term>Farias</term>
<term>Fluminense</term>
<term>Goncalves</term>
<term>Incl</term>
<term>Inst</term>
<term>Janeiro</term>
<term>Kinetic deprotonation step</term>
<term>Lima</term>
<term>Ltmp</term>
<term>Marcelo</term>
<term>Moderate diastereoselectivities</term>
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<term>Pinenebased</term>
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<term>Pinheiro</term>
<term>Quim</term>
<term>Sergio</term>
<term>Stereochemistry</term>
<term>Stereoselectivities</term>
<term>Stereoselectivity</term>
<term>Tetrahedron</term>
<term>Tions</term>
<term>Unexpected decrease</term>
<term>Univ</term>
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<term>Aldol reaction</term>
<term>Alkyl</term>
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<term>Alkylation reaction</term>
<term>Benzaldehyde</term>
<term>Bromide</term>
<term>Chiral</term>
<term>Deprotonation</term>
<term>Diastereoselective</term>
<term>Diastereoselective syntheses</term>
<term>Diastereoselectivities</term>
<term>Enantioselective</term>
<term>Enantioselective syntheses</term>
<term>Enantioselective syntheses diastereoselective syntheses</term>
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<term>Facial stereoselectivities</term>
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<term>Fluminense</term>
<term>Goncalves</term>
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<term>Inst</term>
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<term>Kinetic deprotonation step</term>
<term>Lima</term>
<term>Ltmp</term>
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<term>Stereochemistry</term>
<term>Stereoselectivities</term>
<term>Stereoselectivity</term>
<term>Tetrahedron</term>
<term>Tions</term>
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<front><div type="abstract" xml:lang="en">ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.</div>
</front>
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<affiliations><list><country><li>Brésil</li>
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<tree><country name="Brésil"><region name="État de Rio de Janeiro"><name sortKey="Pinheiro, Sergio" sort="Pinheiro, Sergio" uniqKey="Pinheiro S" first="Sergio" last="Pinheiro">Sergio Pinheiro</name>
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<name sortKey="De Farias, Florence M C" sort="De Farias, Florence M C" uniqKey="De Farias F" first="Florence M. C." last="De Farias">Florence M. C. De Farias</name>
<name sortKey="De Lima, Marcelo B" sort="De Lima, Marcelo B" uniqKey="De Lima M" first="Marcelo B." last="De Lima">Marcelo B. De Lima</name>
<name sortKey="Goncalves, Clara B S S" sort="Goncalves, Clara B S S" uniqKey="Goncalves C" first="Clara B. S. S." last="Goncalves">Clara B. S. S. Goncalves</name>
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